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Self assembling quantum dots (QDs) has been attracted much attention to formstructures with dimensions on the order of a few tensof nm that are necessary for the realization of advanced quantum devices such as quantum cellular automata (QCA) or the quantum computer. To realize these structures, it is necessary to control the location of QDs.

In 1990, we have proposed a novel self-assembling growth method, termed Droplet Epitaxy, for the direct formation ofQDs with homogeneous size[1]. We believe this was the first paper aiming the direct formation ofQDs without using any lithography. The Stranski-Krastanow type growth, which is used by many researchers to fabricate QDs, occurs only in the strained systems such as InGaAs/GaAs. Compared with the island formation based on the Stranski-Krastanow growth mode, the Droplet Epitaxy is applicable to the formation of quantum dots not only in lattice-mismatched but also in lattice-matched systems such as GaAs/AlGaAs. The process of the Droplet Epitaxy in MBE chamber consists of forming numerous III-column element droplets such as Ga or InGa with homogeneous size of around 10 nm on the substrate surface first by supplying their molecular beams, and then reacting the droplets with As molecular beam to produce GaAs or InGaAs epitaxial microcrystals.

However, whenQDs are formed on a planar substrate by using Droplet Epitaxy, they are randomly distributed in the location on the substrate. In this presentation, we report on our recent progress toward the fabrication of site-controlled III-V compound semiconductor QDs by using Droplet Epitaxxy and the lithography based on the Atomic Force Microscopy(AFM).

In order to fabricate nano-hole structures on atomically flat surface for the nucleation sites ofIII-column element droplets in the formation of QDs by Droplet Epitaxy, we combined well-defined AFM tip-induced oxidation and atomic hydrogen-assisted oxide removing technique on GaAs (001).Wehave already reported an atomic hydrogen cleaning effect on surface oxide and contaminants on air-exposed interfaces embedded in GaAs quantum well (QW) [2]. These nano-hole structures fabricated by this method might be act as nucleation sites for theIII-column element droplets in the formation of QDs by Droplet Epitaxy.
Nanomaterials Laboratory, National Institute for Materials Science, Tsukuba, 305-0047,
Japan
Nobuyuki Koguchi
Toward the Fabrication of Site-controlled ‡V-‡X Compound Semiconductor Quantum Dots by Droplet Epitaxy
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